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IB Chemistry · Structure 2: Models of bonding and structure

The covalent model practice questions.

48 exam-style questions on The covalent model — topic S2.2 of Structure 2: Models of bonding and structure in the IB Chemistry syllabus — with answers and explanations. Samples below; the full set is free with an account.

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About this topic

Syllabus code
S2.2
Subject
IB Chemistry
Concept
S2 · Structure 2: Models of bonding and structure
Questions
48 with worked answers
Question types
23 multiple-choice questions · 9 true/false questions · 8 fill-in-the-gap questions · 6 flashcards · 2 matching tasks
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Sample questions on The covalent model

What is the shape of a carbon dioxide (CO₂) molecule?

  • bent
  • linear
  • trigonal planar
  • tetrahedral

Answer: linear

The central carbon has two double bonds and no lone pairs; the two regions of electron density repel to opposite sides, giving a linear O=C=O with a 180° bond angle.

What is the approximate H–N–H bond angle in an ammonia (NH₃) molecule?

  • 90°
  • 104.5°
  • 107°
  • 109.5°

Answer: 107°

Ammonia has three bonding pairs and one lone pair. The lone pair repels more strongly, compressing the bond angle from 109.5° to about 107° (trigonal pyramidal).

Determine the number of lone pairs on the central sulfur atom in a sulfur dioxide (SO2) molecule.

  • 0
  • 1
  • 2
  • 3

Answer: 1

In SO₂ the central S has two bonding regions and one lone pair, giving a bent (V-shaped) molecule.

State the number of sigma (σ) and pi (π) bonds in a molecule of ethyne, C2H2 (H–C≡C–H).

  • 3 σ and 2 π
  • 5 σ and 0 π
  • 2 σ and 3 π
  • 4 σ and 1 π

Answer: 3 σ and 2 π

Two C–H single bonds (2 σ) plus a C≡C triple bond (1 σ + 2 π) give 3 σ and 2 π bonds in total.

Which species has a trigonal planar electron domain geometry around the central atom?

  • NH3
  • H2O
  • BF3
  • CH4

Answer: BF3

BF₃ has three bonding pairs and no lone pairs on boron, giving trigonal planar geometry with 120° angles.

In the Lewis (electron dot) structure of ammonia, NH₃, state the number of bonding pairs and lone pairs on the nitrogen atom.

  • Three bonding pairs and one lone pair
  • Four bonding pairs and no lone pairs
  • Two bonding pairs and two lone pairs
  • Three bonding pairs and two lone pairs

Answer: Three bonding pairs and one lone pair

Nitrogen has five valence electrons; three are shared with hydrogen atoms and the remaining two stay as one lone pair, giving four electron domains in total. The commonest error is to count only the bonds and forget that every unshared pair must still be drawn.

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